Search results for "statistical [methods]"
showing 10 items of 1664 documents
Simulation studies of fluid critical behaviour
1997
We review and discuss recent advances in the simulation of bulk critical phenomena in model fluids. In particular we emphasise the extensions to finite-size scaling theory needed to cope with the lack of symmetry between coexisting fluid phases. The consequences of this asymmetry for simulation measurements of quantities such as the particle density and the heat capacity are pointed out and the relationship to experiment is discussed. A general simulation strategy based on the finite-size scaling theory is described and its utility illustrated via Monte-Carlo studies of the Lennard-Jones fluid and a two-dimensional spin fluid model. Recent applications to critical polymer blends and solutio…
Evaluating Thermal Corrections for Adsorption Processes at the Metal/Gas Interface
2019
International audience; Adsorption and desorption steps are key for active catalysts and rely on a subtle balance between enthalpic and entropic terms. While the enthalpic term is becoming ever more accurate through density functional development, the entropic term remains underrated and its precise determination a great challenge. In this work, we have performed extensive first principles thermodynamic integration (TI) simulations for the 1 adsorption of small (e.g., CO) to larger (e.g., phenol) molecules at metallic surfaces and compared their adsorption free energies to the values obtained by vertical, static statistical mechanics approximations to thermal corrections invoking three diff…
Modeling the Spatial Distribution of Xylella fastidiosa: A Nonstationary Approach with Dispersal Barriers
2022
Spatial species distribution models often assume isotropy and stationarity, implying that spatial dependence is direction-invariant and uniform throughout the study area. However, these assumptions are violated when dispersal barriers are present. Despite this, the issue of nonstationarity has been little explored in the context of plant health. The objective of this study was to evaluate the influence of barriers in the distribution of Xylella fastidiosa in the demarcated area in Alicante, Spain. Occurrence data from 2018 were analyzed through spatial Bayesian hierarchical models. The stationary model, illustrating a scenario without control interventions or geographical features, was com…
Methods to Compute Pressure and Wall Tension in Fluids containing Hard Particles
2011
Colloidal systems are often modelled as fluids of hard particles (possibly with an additional soft attraction, e.g. caused by polymers also contained in the suspension). in simulations of such systems, the virial theorem cannot be straightforwardly applied to obtain the components of the pressure tensor. In systems confined by walls, it is hence also not straightforward to extract the excess energy due to the wall (the "wall tension") from the pressure tensor anisotropy. A comparative evaluation of several methods to circumvent this problem is presented, using as examples fluids of hard spheres and the Asakura-Oosawa model of colloid-polymer mixtures with a size ratio $q=0.15$ (for which th…
A Supervised Learning Framework for Automatic Prostate Segmentation in Trans Rectal Ultrasound Images
2012
International audience; Heterogeneous intensity distribution inside the prostate gland, significant variations in prostate shape, size, inter dataset contrast variations, and imaging artifacts like shadow regions and speckle in Trans Rectal Ultrasound (TRUS) images challenge computer aided automatic or semi-automatic segmentation of the prostate. In this paper, we propose a supervised learning schema based on random forest for automatic initialization and propagation of statistical shape and appearance model. Parametric representation of the statistical model of shape and appearance is derived from principal component analysis (PCA) of the probability distribution inside the prostate and PC…
Multiple Mean Models of Statistical Shape and Probability Priors for Automatic Prostate Segmentation
2011
International audience; Low contrast of the prostate gland, heterogeneous intensity distribution inside the prostate region, imaging artifacts like shadow regions, speckle and significant variations in prostate shape, size and in- ter dataset contrast in Trans Rectal Ultrasound (TRUS) images challenge computer aided automatic or semi-automatic segmentation of the prostate. In this paper, we propose a probabilistic framework for automatic initialization and propagation of multiple mean parametric models derived from principal component analysis of shape and posterior probability information of the prostate region to segment the prostate. Unlike traditional statistical models of shape and int…
Analysis of an Experimental Model of In Vitro Cardiac Tissue Using Phase Space Reconstruction
2014
International audience; The in vitro cultures of cardiac cells represent valuable models to study the mechanism of the arrhythmias at the cellular level. But the dynamics of these experimental models cannot be characterized precisely, as they include a lot of parameters that depend on experimental conditions. This paper is devoted to the investigation of the dynamics of an in vitro model using a phase space reconstruction. Our model, based on the heart cells of new born rats, generates electrical field potentials acquired using a microelectrode technology, which are analyzed in normal and under external stimulation conditions. Phase space reconstructions of electrical field potential signal…
Naturally constrained reduced form and stuctural parameters estimation
1988
To characterize such a situation, we introduce the concept of a "natural constraint", which is presented and discussed is section 1 of the present paper. Section 2 is concerned with the efficient estimation of the naturally constrained reduced form. From it, we derive efficient estimators of the structural parameters (by indirect GLS) and propose a simple test of the a priori restrictions. In section 3 we discuss estimation by 2SLS. In addition to the resultsobtained by Turkington and Pesaran, we develop a 2SLS-GLS estimator and assess its asymptotic properties. Several full information estimatorsof the 3SLS type are presented and compared in section 4 and some efficiency aspects of the ins…
Taking digitized points quality into account in geometrical specification measurement by laser sensor
2004
International audience; Today, the new measurement techniques without contact like the laser sensors are used more and more in industrial applications. They allow to obtain many points in a short time. However these techniques have a less good accuracy than the classical process with contact probe for metrology application. The work presented in this paper, is part of a research project on the in-process product inspection. In the case of in-process product inspection, the throughput time must be the shortest with a good dimensional accuracy. So, it is necessary to increase the measurement accuracy of the points cloud for using the laser scanners. For this first approach, we suggest to buil…
Emergence of rogue waves from optical turbulence
2011
International audience; We provide some general physical insights into the emergence of rogue wave events from optical turbulence by analyzing the long term evolution of the field. Depending on the amount of incoherence in the system (i.e., Hamiltonian), we identify three turbulent regimes that lead to the emergence of specific rogue wave events: (i) persistent and coherent rogue quasi-solitons, (ii) intermittent-like rogue quasi-solitons that appear and disappear erratically, and (iii) sporadic rogue waves events that emerge from turbulent fluctuations as bursts of light or intense flashes.